種別 Paper
主題 DEVELOPMENT OF HIGHLY DURABLE CONCRETE
副題
筆頭著者 Masaharu SAKUTA
連名者1 Itoshi IZUMI
連名者2 Kyoichi TANAKA
連名者3 Masashi SUGIYAMA
連名者4  
連名者5  
キーワード
9
2
先頭ページ 645
末尾ページ 650
年度 1987
要旨 1.INTRODUCTION
In an ordinary atmospheric environment, corrosion of reinforcing steel in a concrete structure can occur when carbon dioxide permeates the concrete and the protective film of the steel is destroyed. Thus the rate of carbonation in concrete can be a significant factor in influencing the durability of the concrete structure. In urban areas, such as Tokyo or Osaka, sulfurous acid gas from the exhaust of automobiles is diffused in the atmosphere which greatly lowers the pH of rainwater falling in these areas. The penetration of this rainwater into concrete surfaces hastens the carbonation of the conerete and creates a problem. According to the results ofrecent measurements, the pH of rainwater in the Tokyo district is about 3.0. There have been many examples of exposed concrete surfaces being attacked by the strong acidity(1).
Since carbonation of concrete results from the reaction between carbon dioxide and sulfurous acid in the atmosphere and calcium hydroxide in cement hydration products, the predominant concept in the past had been that this reaction was unavoidable. In view of this situation, the authors conducted studies principally on the use of chemical actions with the objective of providing a means of prolonging the lives of concrete structures by reducing the rate of carbonation.

5.CONCLUSIONS
1) The progress of carbonation and penetration of chloride ions are extremely slow in concrete containing the glycol ether derivative.
2) An amino alchohol derivative used for desulfurization and deoxidization during petroleum refining demonstrates an ability to absorb carbon dioxide and chloride ions even when added to mortar or concrete.
3) Carbonation and penetration of chloride ions in mortars containing these amino alchohol derivatives proceed at an extremely slow rate.
4) Through the life expectancy system for reinfroced concrete structure it was estimated that the life of the structure could be prolonged to several hundred years by utilization of these two derivatives.
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